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It may be that SHMO expectations are in error here and that the greater basicity of the carbonyl oxygen is simply a re ection of the greater stability of the protonated carbonyl intermediate as compared to the protonated alkene, as discussed in 7 186 Besseau, F; Lucon, M; Laurence, C; Berthelot, M, J Chem Soc Perkin, 1998, 2, 101 108 187 Saied, O; Bachand, B; Wuest, J D, Can J Chem, 1998, 76, 490 497 188 Rauk, A; Hunt, I R; Keay, B A, J Org Chem, 1994, 59, 6808 6816 189 For a study of hydride reductions, see Wu, Y-D; Tucker, J A; Houk, K N, J Am Chem Soc, 1991, 113, 5018, and references therein 190 Liebman, J F; Pollack, R M, J Org Chem, 1973, 38, 3444.

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191 Hoz, S, J Org Chem, 1982, 47, 3545 192 Shustov, G V, Acad Sci U S S R Proc Chem, 1985, 280, 80..

Our visual perception of the Universe comes from electromagnetic radiation, and such radiation, at a large variety of frequencies, pervades the Universe. In the quantum mechanical view of light, it can be thought of as made up of individual particles - like packets of energy - known as photons and usually indicated by the symbol '). Photons propagate, naturally enough, at the speed of light; since they have zero rest mass their total energy is always given by their kinetic energy, and is related to their frequency f by

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5. Click the Next button to begin the removal process, which also creates a backup item so that Spy Sweeper can reverse any changes later, if you choose. This produces the Step 3: Results screen shown in Figure 7-12, which shows you what the program has done as a result of your latest scan and clean-up operations. Simply click the Finish button, and you re done!

In bleaching, colored impurities that did not scour out are decolorized by an oxidation process typically involving peroxide at high pH. The pollutants from this process are minimal. Impurities in the goods have been previously removed in desizing and scouring, and the reaction product of the peroxide reaction is water. The main pollutant is a large volume of wastewater. There is a minor amount of pollution associated with the use of bleaching chemicals (e.g., silicate, sequesterant, and surfactant).

Figure 6-34: Acrobat 5.0 supports multiple layers and transparency. I created the illustration with separate layers for text, transparency, and the background image.

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Many powerful computers are also relatively small so, in some cases, it may be possible for someone to simply pick up your server and walk away with it If the computer is too large to carry away, a few minutes with a screwdriver will allow just about anyone to remove the hard drive Keeping your database server in a separate of ce that s accessible by an internal network provides some extra security Even if you lock the network down so Internet hackers can t nd a seam to open, you should also consider outgoing connections An employee can probably email data outside of your system or surf to a Web site that allows le uploading Laptop security is a particularly tricky issue these days Laptops are designed for portability.

for t R+ with equality iff A is normal. (Any A Cn n is normal iff AH A = AAH .) Thus, it appears that normal matrices are generally the least troublesome with respect to computing eAt . From the de nition of a normal matrix we see that real-valued, symmetric matrices are an important special case. Of the less dubious means to compute eAt , Golub and Van Loan s algorithm 11.3.1 [4] is suggested. It is based on Pad approximation, which is the use of e rational functions to approximate other functions. However, we will only refer the reader to Ref. 4 (or Ref. 7) for the relevant details. A version of Algorithm 11.3.1 [4] is implemented in the MATLAB expm function, and MATLAB provides other algorithm implementations for computing eAt . 11.4 THE POWER METHODS In this section we consider a simple approach to determine the eigenvalues and eigenvectors of A Rn n . The approach is iterative. The main result is as follows. Theorem 11.11: Let A Rn n be such that (a) A has n linearly independent eigenvectors x (k) , corresponding to the eigenpairs {( k , x (k) )|k Zn }. (b) The eigenvalues satisfy n 1 R with | n 1 | > | n 2 | | n 3 | | 1 | | 0 | ( n 1 is the dominant eigenvalue). If y0 Rn is a starting vector such that

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