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Prior to the introduction of rapid, nondestructive quality monitoring tools, there were few alternatives for ef cient quality assurance except to rely on batch release criteria, such as the wellknown US Pharmacopeia (USP) 905 procedure, which were based on extremely limited sampling (ie, assay 10 individual dosage units from a 30-unit sample of a production-scale batch)..

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, J Chem Phys, 1934, 2, 128 (b) Badger, R M, J Chem Phys, 1935, 3, 710 (c) Gordy, W, J Chem Phys, 1946, 14, 305 92 (a) Mack H G; Christen, D; Oberhammer, H, J Mol Struct, 1988, 190, 215 (b) Christen, D; Gupta, O D; Kadel, J; Kirchmeier, R L; Mack, H G; Oberhammer, H; Shreeve, J M, J Am Chem Soc, 1991, 113, 9131 93 R ggen, I; Dahl, T, J Am Chem Soc, 1992, 114, 511, and references therein 94 David, S; Eisenstein, O; Hehre, W J; Salem, L; Ho mann, R, J Am Chem Soc, 1973, 95, 3806 95 Laube, T; Hollenstein, S, J Am Chem Soc, 1992, 114, 8812 8817, and references therein 96.

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ShopSmart.com is an award-winning e-business that provides a shopping portal where consumers can compare prices o n a wide range of products. In a surprisingly short period, its achievements have included becoming the UK s leading shopping portal, with over three million page views in August 2 0 0 0 ; becoming one of the UK s leading online retailers together with Jungle, Amazon. co.uk, Amazon.com and Streets Online, and being the first dot-com t o offer price comparisons in the U K . ShopSmart.com achieved this by focusing its marketing and market development activities on a continuous yet relatively inexpensive and cost-effective campaign. Some of the factors behind its success are described below: A focus on three core business objectives: to become part of the consumer s everyday life, t o develop a perception of reliability so that customers feel that the business is established and have any concerns about online shopping allayed by the brand, and t o communicate rhe fact that it is about shopping. (This last point may seem trite, yet it is one of the most commonly quoted concerns about many online businesses that have encountered problems, such as Boo.com and Clickmango.com. Unlike these, ShopSmart does exactly what it say^.) T h e effective, practical translation of these objectives into a marketing plan with t wo prongs: awareness building and communicating the benefits of shopping with ShopStnart. The adoption of a shopping bag as its logo highlights an approach favouring the realistic

For a review of the structural consequences of hyperconjugation, see Radom, L, Prog Theor Org Chem, 1982, 3, 1 97 Zurawski, B; Ahlrichs, R; Kutzelnigg, W, Chem Phys Lett, 1973, 21, 309 98 (a) Raghavachari, K; Haddon, R C; Schleyer, P v R; Schaefer III, H F, J Am Chem Soc, 1983, 105, 5915 (b) Yoshimine, M; McLean, A D; Liu, B; DeFrees, D J; Binkley, J S, J Am Chem Soc, 1983, 105, 6185 99 (a) Hawthorne, M F, Acc Chem Res, 1968, 1, 281 (b) Lipscomb, W N, Acc Chem Res, 1973, 6, 257 100 Walsh, A D, Trans Faraday Soc, 1949, 45, 179 101 For a discussion of the bonding in cyclopropane and other molecules with ``bent'' bonds, see Wiberg, K B, Acc.

places galaxies are clearly grouped into clusters of galaxies; a famous example is the Coma cluster of galaxies II is about 100 Mpc away from our own galaxy, and appears in Figure 22 as the dense region in the centre of the map The left panel of Figure 23 shows an optical telescope image of Coma; although the image resembles a star field each point is a distinct galaxy Coma contains perhaps 10000 galaxies mostly too fainllO show in this image omitting in their common gravitational field However, most galaxies sometimes called field galaxies are not part of a cluster Galaxy clusters are the largest gmvitationally-collapsed objeclS in the Universe and they themselves are grouped into superclusters perhaps joined by filaments and walls of galaxies In between this 'foamlike' structure lie large voids, some as large as 50 Mpc across.

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